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Creating Bootable Partitions:Before creating a partition where you plan to install an operating system (a bootablepartition), you should understand the following information.With the exception of DOS 6.22 (or earlier), partitions beyond 8 GB are visible to the current operating system. For more information, see “Understanding the BIOS 1,024 Cylinder (8 GB) Limit” and “Understanding the 2 GB Boot Code Boundary” in Help.
Also, it may be that you need to put your DOS partition at the beginning of the drive in order to be bootable. (DOS had more limitations than newer OP systems, as you know) but I'm not sure that the location at the end of the physical drive would prevent DOS from seeing the drive.