Okay, so I rebooted in safe mode and was still unable to access the folders I wanted to by just clicking.
But I was able to erase the previous user account that held permissions for the files I wanted which allowed me further access into the folder.
This got me into the next layer of folders, but again I was unable to proceed further then that.
I decided to fiddle around with steps 1 - 3 again on this new folder;
1. Right-click the folder that you want to take ownership of, and then click Properties.
2. Click the Security tab, and then click OK on the Security message (if one appears).
3. Click Advanced, and then click the Owner tab.
Although when I clicked on the Security tab I received this message, "You do not have permission to view or edit the current permission settings for (Folder Name), but you can take ownership or change audit settings."
Deciding to forge on through I clicked on Advanced, then the Owner tab, chose my profile and checked the "Replace owner on subcontainers and objects" box. This allowed me full access.
The only problem with this is that I now have to do this with each other folder. But hey I'm not able to access all my junk.
Thank you everyone for your replies and helpful advice.