Thanks for the confirmation. The standoffs should be fine, the old motherboard (My dad picked up a virus that fried the bios on it years back) came out and the new one went in using the same ones, and I don't think overheating would be the problem quite that quickly, although that's just my thought. I have experienced an overheated board before, I've had the system fan on my laptop stop working a couple times. (Just needed a good cleaning, fortunately) It, at least, doesn't restart after an overheat. This one, I hit the power button, the lights come on, the fan turns on, and then it all dies. And repeat.
I was planning on getting a 6-700 watt psu eventually, (among other upgrades) but it's not in the budget, atm, and I just wanted to get it up and running, cause even at onboard basics, it'll be faster than my old laptop (Poor thing's had a rough life)