Do not install old after new, install NEW AFTER OLD.If you don't, the old will never work. Maybe a BOOTMGR deleted? Hal.dll, NTOSKRNL, C_437 errors? Config/software, config/sam, config/default, config/system errors? Crashes? What exactly is happening? Is there any "FATAL: Could not read from boot medium! System halted.", or "FATAL: No bootable medium found! System halted." errors?
Try booting from the CD, waiting, pressing R, selecting your XP installation, typing in the admin password, then type in fixmbr and hit enter.
When it warns you, hit Y and press enter.
Next, type in fixboot and press enter.
Again, press Y and hit enter.
Next. type exit and hit enter.
See if booting into the XP works now.