kcbennet89
Did this get solved for you in the chat room? Don't remember if it was the power switch or not. Anyway, if it didn't get solved, I'd go with what Dave recommended. I've had plenty of PSUs that have seemed totally workable and still not gotten the PC on for whatever reason.
Also consider that all of the power for the PC comes from the PSU, so it's going to get the most stress and is exposed to the greatest risk electrically speaking. I'd say about 70+% of the time I've had odd issues like that the PSU has been the culprit. 20% of the time it's been problems with the graphics card, so you could also try removing the GPU and booting up without it to see if that does anything. The rest of the time it's been damage to multiple components, and there wasn't a single piece that could be blamed.