As BC stated; The glitch is caused by this:
I've actually had this problem under a pure DOS environment as well. Hooked the system up to an old hard drive and did a full MS DOS 6.22 install from the ground up and the games still threw a fit.
It's odd and, under further inspection, seems to effect only old Maxis installers?
Weird and annoying, but not exactly a massive problem with the system.
Still, I can only wonder what might be the issue. It's probably something dumb like whatever clever text Maxis was trying to pull, it doesn't sit right with some component somewhere within my PC.
As it's been said, it's no doubt my fault for going a little too modern with the hardware for a dedicated 90s gaming system.
But, thankfully, I found the windows version of Simcity and Simcity 2000, so disaster (partially) adverted!
Thanks for your input, everyone.