Sorry about that... was pressed for time when posting this earlier, but can explain better now.
System that has this issue is a system that I have running as a file server mainly, among other duties it serves for processing video encoding raw video files so that my main system isnt lagged out through processing videos of captured online game events in which I take like 20GB Fraps video files and vdub process them to a better smaller avi format to share online on youtube.
The 2nd NIC's of these systems is used mainly as a direct network connection to transfer large amounts of data between the systems without affecting the rest of my home network with others who are streaming netflix or trying to use the Vonage phone at the same time.
System Specs are:
Computer #1 - Acts as a File Server / Processing of Large Video Files etc
Athlon X2 215 2.7Ghz
2GB DDR3 1333Mhz
GeForce GT430 PCIE16 video card with 1GB RAM
Drive 1 = 60GB SATA ( Laptop Hard Drive Multi Partition for Linux and Windows XP Pro SP3 and Grub managing the bootloader)
Drive 2 = 500GB SATA II ( Data & Data Processing Drive )
Network Adapter # 1 = nVidia Integrated NIC ( Connected to Router with IP Reservation / Internet Access )
Network Adapter # 2 = Intel Pro 100+ Managed PCI NIC ( Cross over Cable to gaming Computer #2 Static IP )
Computer #2 - Gaming System / Capturing Live Game Content with Fraps
Athlon II x4 620 2.6Ghz
8GB DDR3 1600Mhz
ASUS ATI HD5450 PCIE16 video card with 1GB RAM
Drive 1 = 240GB SATA II Corsair SSD ( OS Windows 7 64-bit & Games )
Drive 2 = 500GB SATA II (Data & Location that Fraps saves large video files to that are captured from in game )
Network Adapter # 1 = Realtek 100 NIC Integrated ( Connected to Router dynamic IP no reservation / Internet Access )
Network Adapter # 2 = Intel Pro 100+ Managed PCI NIC ( Cross over Cable to Server Computer #1 Static IP )
So computer #1 states that its using the Intel Pro 100+ Managed NIC, yet its clearly using the integrated nVidia NIC. NIC #2 which is the Intel Pro shows no link and no activity. Computer #2 can not ping Computer #1 through the cross over, because the Intel Pro 100+ Managed NIC is not functioning. Yet Computer #1 is communicating through the nVidia NIC and yet in Device Manager and IP config it states that its the Intel Pro 100+ Managed NIC that its using.
Never ever have I seen such an oddity with Windows XP Pro SP3 and a NIC not functioning and another functioning as it.
Lastly Linux is on this Computer #1 system so that when I am not processing files or using it as a file server, it acts as my Linux Workstation.
Everything was working fine up until I decided to replace Fedora 20 with Mint 16 on a different partition of Drive #1. Upon the reboot after this is when this strange Network Hardware/OS issue occurred with Windows XP Pro SP3 on that same system to where the system is seriously confused. And the strangest part about this is that Linux should not have affected the Windows partition to cause any corruption.
One process I was thinking I could try before a full rebuild is to remove this NIC #2 from Computer #1 and boot the system and then shut down and then reintroduce the NIC #2 and maybe it will detect the hardware change and straighten itself out. Otherwise its looking like a clean install of Windows to the first partition and then Linux Mint build its partition(s) to the unallocated space is what I will have to do.