You will need to install a media service on that computer for the TV to detect. Then once detected it should then be able to navigate though directory tree or user interface depending on what service you use. Content to view would have to be in the supported content formats of the TV, otherwise files will not show or wont play.
If you want to clone your display to the tv for games etc, I would go with a HDMI connection or at the least a VGA connection if supported.
