booting from a USB device can be tricky, and, frankly, i have never tried to boot windows from an external drive, nor do i intend to, however, i do know that on a lot of motherboards, booting from a USB device is possible. however, even though some systems claim to be able too, they cant, they just lock up in the boot sequence or do not boot at all. it all depends on the hardware and software, as with the rest of the computer.