Have you double checked the connections from the power switch to the motherboard?
Do you know if the onboard video was used in this motherboards last setup or a video card? If a video card had been used the BIOS may be set to send video through the card. If you refer to the motherboard manufacturer's documenation you can determine how to use a jumper on the motherboard to reset the BIOS to its default.
Are there any system beeps when the computer powers up?
What is the wattage of the power supply?
How many other devices are in the computer? (CD/DVD drives, hard drives)