So people could have some how adapted or something and they could have somehow had something to breathe. Maybe they didnt need oxygen
this is the dumbest thing I've ever heard.
I take it you haven't learned WHY we need oxygen? you know, it's role in metabolism?
the only way a organism could breathe another element/compound would be if it's entire anatomy was changed from a Carbon based life-form to something else.
But the other prospective elements (silicon, sulphur) are either to unstable or simply too inert to form the necessary compounds that promote self-sustaining metabolism.
Not to mention that such a radical change is not possible via evolution- the entire chain has to evolve that way; eg; right from the primordial soup.