Taking a quick look at the product page, it supports .MP4 but not MKV for it's own video features, so given your MKV file remained unchanged, I suspect that the device itself may be internally cataloging supported file types, renaming them to a hash or something.
How to stop it though, I've not found anything on that. It's difficult to predict how these "Smart" External Hard Drives will behave sometimes, and any inbuilt functionality like this is definitely not well documented to the point of knowing how to prevent it in most cases.