MIRKOSOFT,
Good idea!
Second drive is the DVD slot is great use of a laptop.
Most of the time you never need the CD/DVD anyway. And if you do, a small portable drive on USB will work for the few times yu need it.
To boot DOS, it must be first primary and use FAT but not FAT 32.
Older DOS versions can not read FAT 32. And older DOS can not read beyond 8GB. That is why you want it to be first on the drive.