Vent holes are designed for intake, not exhaust... Air will enter the computer through intake vents, intake fans, and airflow will be mostly in the direction of the dominant exhaust fan.. Typically this is the psu exhaust fan, although some system do use that extra fan on back like your setup.. But in your case it doesn't seem to be working...
Is there available space for a front/inside fan, for intake? This may help balance the air flow problem...