Well...
copy [long_path] \\additional /y
\\additional is the name of a computer; you also need the name of a folder
You want to copy something to a folder in the computer "\\additional"; that folder it's a share; you can see the valid names you can use by verifying the share names on that computer. For example, on the computer called "additional" you have the following shares:
a -- which on additional computer is in fact: c:\dir1\share1 folder
b -- --II-- c:\dir1\share2
To copy to one of those folders:
copy \\main\c\dir0\dir1\dir2\dir3\dir4\file.txt \\additional\a /y
And yes, it is a filename length restriction: 256 characters maximum for a path (if I remember well).
So, if your [long_path] has more than 256 characters, you have to do something to reduce it.