When u have a single PCIe x16 slot, 16 lanes are active. When is SLi or CrossFire each slot is reduced to 8 lanes, because there is no need for 16 lanes for any card on the market. The reason that they do this is somewhat because of power reasons, as there is only 6A allocated to the PCIe slot(s) and 8 lanes will take less power than 16, so having 32 would be too much and each card would not get enough.
This dosent have any effect on any card before the 8800 GTS/GTXs, wich cannot run on 8 lanes, but actually need 16 lanes in SLi mode and there are some motherboards that do have x16 in SLi mode instead of x8.